NMR study of ammonium magnesium langbeinite.

نویسندگان

  • Campbell
  • Stokes
  • Boerio-Goates
چکیده

Recent studies have shown that ammonium langbeinites have low-temperature phase transitions uncharacteristic of the rest of the langbeinite family. In this study, proton NMR spin-lattice relaxation times Ti and spin-spin relaxation times T2 for powder samples of (NH4)2Mg2(S04)s are reported in the temperature range from 77 to 373 K. The ammonium ions occupy two different kinds of sites in the crystal. The measured barrier to thermally activated ammonium reorientations is found to be 2.0 and 3.3 kcal/mol for the two sites, respectively. Additionally, there is no observable discontinuity in Tz at the reported phase transition at 161 K, in agreement with heat-capacity studies, suggesting that the transition mechanism may be dig'erent from those of most langbeinites.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Investigation of the effect of phosphate agent type on setting time, flowability, hydration and dehydration of magnesium phosphate cement.

Magnesium phosphate cements (MPC) are the most developed kind of chemically bonded ceramics which form through the reaction of magnesium oxide and soluble phosphate salts. Therefore, study of different magnesium phosphate cement systems is considered important according to the type of phosphate agent used. In this study, effect of mono-ammonium phosphate (MAP), di-ammonium phosphate (DAP), and ...

متن کامل

Evidence for struvite in poultry litter: effect of storage and drying.

The use of spectroscopic techniques (especially phosphorus-31 nuclear magnetic resonance [(31)P-NMR] and X-ray absorption near edge structure spectroscopy) has recently advanced the analysis of the speciation of P in poultry litter (PL) and greatly enhanced our understanding of changes in P pools in PL that receive alum (aluminum sulfate) to reduce water-soluble P and control ammonia emissions ...

متن کامل

Improving methodology for the preparation of highly substituted imidazoles using nano-MgAl2O4 as catalyst under microwave irradiation

An efficient synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles by one-step condensation of  an aldehyde, benzil, ammonium acetate and primary amine in the presence of nanocrystalline magnesium aluminate under microwave irradiation is described. The advantages of this catalyst are including simple work-up, low cost and reusability. Compared with conventional methods, the ...

متن کامل

Improving methodology for the preparation of highly substituted imidazoles using nano-MgAl2O4 as catalyst under microwave irradiation

An efficient synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles by one-step condensation of  an aldehyde, benzil, ammonium acetate and primary amine in the presence of nanocrystalline magnesium aluminate under microwave irradiation is described. The advantages of this catalyst are including simple work-up, low cost and reusability. Compared with conventional methods, the ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Physical review. B, Condensed matter

دوره 51 17  شماره 

صفحات  -

تاریخ انتشار 1995